Effects of strain on the corrosion behaviour of X80 steel

The effects of strain on the corrosion behaviour of X80 steel in 0.62 M NaCl aqueous solution were investigated in the present paper. An increase in strain causes the corrosion resistance of the specimen to present a down and up trend, with the lowest point at about 1.0 × 10⁻³. When the strain increases further, corrosion resistance decreases again until the strain reaches 5.5 × 10⁻³. After that, corrosion resistance improves with the increase in strain and tends to be relatively stable. The variation of corrosion resistance has much to do with the surface activity and behaviour of dislocation on the surface of the specimen.     

Methionine restriction up‐regulates the expression of the pi class of glutathione S‐transferase partially via the extracellular signal‐regulated kinase‐activator protein‐1 signaling pathway initiated by glutathione depletion

Understanding the molecular events underlying gene regulation by amino acids has attracted increasing attention. Here, we explored whether the mechanism by which methionine restriction affects the expression of the π class of glutathione S‐transferase (GSTP) is related to oxidative stress initiated by glutathione (GSH) depletion. Rat primary hepatocytes were cultured in an L‐15‐based medium in the absence or presence of 200 μM L ‐buthionine sulfoximine (BSO) or in a methionine‐restricted L‐15 medium supplemented with 20 μM L ‐methionine up to 72 h. BSO and methionine restriction time‐dependently induced GSTP mRNA and protein expression in a similar pattern accompanied by a decrease in the cellular GSH level. The phosphorylation of extracellular signal‐regulated kinase (ERK), but not of c‐Jun NH₂‐terminal kinase and p38, was stimulated by methionine restriction and BSO. Electromobility gel shift assay showed that the DNA‐binding activity of nuclear activator protein‐1 (AP‐1) increased in cells exposed to methionine restriction or BSO. With the ERK inhibitor FR180204, AP‐1 activation and GSTP expression were abolished. Moreover, the induction of GSTP by methionine restriction and BSO was reversed by GSH monoethyl ester and N‐acetylcysteine. Our results suggest that methionine restriction up‐regulates GSTP gene expression, which appears to be initiated by the ERK‐AP‐1 signaling pathway through GSH depletion in rat hepatocytes.     

垂直阵列DL巴间准直光束指向精度测量方法

简介了大功率二极管激光器垂直阵列巴条(Bar)间准直光束指向精度问题,及其对激光器垂直阵列输出光束的影响.采用单透镜远场探测系统对激光器垂直阵列远场光斑进行采集,搭建了实验测试装置.结合光斑强度质心算法对实验室封装的20巴条连续输出2 kw二极管激光器垂直阵列进行了测量,测试结果为巴间准直光束指向精度±1.7 mrad...     

新型含氟丙烯酸酯共聚乳液及其表面性能研究

以十二烷基硫酸钠(SDS)、全氟辛基磺酸钾(FC-80)和脂肪醇聚氧乙烯醚(AEO-9)为混合乳化剂,制备了一系列不同含氟量的含氟丙烯酸酯(FA)-丙烯酸丁酯(BA)共聚乳液,系统研究了不同反应条件对于乳液共聚的动力学影响,利用红外光谱和核磁共振波谱确认了共聚物的分子结构,利用接触角的测定研究了共聚物膜表面的性能.结果...     

D4/D4Vi阴离子开环乳液共聚动力学及乳胶粒径

采用阴离子开环乳液聚合法制备了聚硅氧烷共聚乳液,研究了反应条件对共聚动力学及乳胶粒径的影响。结果表明,初始恒速阶段的表观动力学方程为Rp=k[E]0.18[KOH]0.59[M]0.75,表观活化能为52.77 kJ/mol。乳胶粒径随反应温度升高而变小,粒径分布在80℃出现最小值。随[KOH]的增大,乳胶粒径变大,粒径分布变宽。复合乳化剂质量浓度[E]在不同范围内对乳胶粒径及其分布的影响不同,当[E]<0.0572 g/mL时,随[E]增大,乳胶粒径变小,粒径分布变窄;当[E]>0.0572 g/mL时,乳胶粒径反而变大。     

ICP-MS法测定地电化学(泡塑)样品中痕量金

通过实验验证了在酸性介质存在条件下用ICP-MS法测定地电化学(泡塑)样品中痕量金的可行性,在稀释因子存在条件下得到了方法的检出限为3 ng、精密度为1.40％.同时,通过制备模拟负载不同金含量的泡塑样品,计算加入标准物质回收率为88.80％～107.37％;与GAAS法测定结果进行显著性检验发现两组数据之间无显著性差...     

六流方坯中间包内流场的数值模拟及优化

以唐钢150mm×150mm铸坯6流T型中间包为研究对象,用商业软件ANSYS对中间包内钢液流场进行了三维数值模拟与优化,研究了中间包内钢液的流动特征和设置导流挡墙后中间包内钢液的流动方式。结果表明,设置合理的挡墙和导流孔可以有效改善中间包冶金效果;3个导流孔直径(mm)分别为93、72、36,位置(mm)为(220,140)、(350,280)、(700,300),倾斜角度为(21°,15°)、(8°,23°)、(10°,28°)时中间包流场最为合理。     

微波加热钢渣脱磷的升温特性

采用微波碳热还原方法,对钢渣进行脱磷处理.在实验室条件下,对钢渣的升温特性进行研究.试验表明不同组成钢渣在微波中均具有很好的升温特性和较好的脱磷效果.结合脱磷效果与升温特性,确定了微波处理钢渣的工艺参数.     

低密度碳气凝胶制备及其热学、力学性能研究

ICF及X光激光实验将结构和密度可调的碳气凝胶作为一种常用靶材料,其力学、热学性能和结构直接影响其应用。本文以间苯二酚（R）和甲醛（F）作为反应前驱体,通过调节反应参数和控制制备条件合成了低密度（<50mg/cm³）碳气凝胶,最低密度为36mg/cm³。利用场发射扫描电镜（FESEM）、X射线衍射仪、孔径分布及比表面积测试仪和同步热分析仪等对低密度碳气凝胶的结构进行研究;采用动态力学分析仪、电子拉伸试验机和热传导分析仪对其性能进行表征。研究表明,该低密度碳气凝胶具有明显珍珠项链状纳米网络,颗粒大小均匀,粒径约为70nm,比表面积达1217m²/g;在-120～200℃温区内,具有稳定的力学性能,杨氏模量仅为0.375MPa,是一种理想的弹性材料。常规密度碳气凝胶材料为几十MPa。在室温空气气氛下,其热导率低至0.05W/(m•K),相对于常规碳气凝胶有较大改善。